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KurtCobain 04-21-2011 10:11 PM

It is not always easy to make sensible comparisons between the elements however as some bonds are quite short because of multiple bonding (for instance the O=O distance in O2 is short because of the the double bond connecting the two atoms.

KurtCobain 04-21-2011 10:12 PM

There are several other ways ways to define radius for atoms and ions. Follow the appropriate hyperlinks for literature references and definitions of each type of radius. All values of radii are given in picometres (pm). Conversion factors are:

KurtCobain 04-21-2011 10:12 PM

1 pm = 1 x 10-12 metre (meter)
100 pm = 1 Ångstrom
1000 pm = 1 nanometre (nm, nanometer)
Neutral radii

KurtCobain 04-21-2011 10:12 PM

The size of neutral atoms depends upon the way in which the measurement is made and the environment.

KurtCobain 04-21-2011 10:13 PM

Follow the appropriate hyperlinks for definitions of each radius type. The term "atomic radius" is not particularly helpful although its use is widespread. The problem is its meaning,
Be(II) 31

KurtCobain 04-21-2011 10:13 PM

which is clearly very different in different sources and books. Two values are given here, one is based upon calculations and the other upon observation - follow the appropriate link for further details.

KurtCobain 04-21-2011 10:14 PM

Atomic radius (empirical): 105 pm

KurtCobain 04-21-2011 10:15 PM

Atomic radius (calculated): 112 pm

KurtCobain 04-21-2011 10:15 PM

Covalent radius (2008 values): 96 pm

KurtCobain 04-21-2011 10:19 PM

Molecular single bond covalent radii: 102 (coordination number 2) pm

KurtCobain 04-21-2011 10:20 PM

Molecular double bond covalent radii: 90 pm

KurtCobain 04-21-2011 10:21 PM

Molecular triple bond covalent radii: 85 pm

KurtCobain 04-21-2011 10:22 PM

Covalent radius (empirical): 90 pm

KurtCobain 04-21-2011 10:22 PM

van der Waals radius: no information pm

KurtCobain 04-21-2011 11:59 PM

Beryllium ( /bəˈrɪliəm/ bə-RIL-ee-əm) is the chemical element with the symbol Be and atomic number 4.

KurtCobain 04-21-2011 11:59 PM

A divalent element, beryllium occurs naturally only in combination with other elements in minerals.

KurtCobain 04-22-2011 12:00 AM

Notable gemstones which contain beryllium include beryl (aquamarine, emerald) and chrysoberyl.

KurtCobain 04-22-2011 12:00 AM

The free element is a steel-gray, strong, lightweight and brittle alkaline earth metal.

KurtCobain 04-22-2011 12:00 AM

It is primarily used as a hardening agent in alloys, notably beryllium copper.

KurtCobain 04-22-2011 12:01 AM

Structurally, high flexural rigidity, thermal stability and thermal conductivity as well as low density (1.85 times that of water) make beryllium a superior aerospace material for high-speed aircraft, missiles, space vehicles and communication satellites.

KurtCobain 04-22-2011 12:01 AM

Because of its low density and atomic mass, beryllium is relatively transparent to X-rays and other forms of ionizing radiation, and therefore is the most common window material for X-ray equipment and in particle physics experiments.

KurtCobain 04-22-2011 12:01 AM

Commercial use of beryllium metal presents technical challenges due to the toxicity (especially by inhalation) of beryllium-containing dusts.

KurtCobain 04-22-2011 12:02 AM

Beryllium produces a direct corrosive effect to tissue, and can cause a chronic life-threatening allergic disease called berylliosis in susceptible persons..

KurtCobain 04-22-2011 12:02 AM

Because it is not synthesized in stars, beryllium is a relatively rare element in both the Earth and the universe.

KurtCobain 04-22-2011 12:02 AM

The element is not known to be necessary or useful for either plant or animal life

KurtCobain 04-22-2011 12:02 AM

Contents [hide]

KurtCobain 04-22-2011 12:03 AM

1 Characteristics

KurtCobain 04-22-2011 12:03 AM

1.1 Physical properties

KurtCobain 04-22-2011 12:04 AM

1.2 Nuclear properties

KurtCobain 04-22-2011 12:04 AM

1.3 Isotopes and nucleosynthesis

KurtCobain 04-22-2011 12:04 AM

1.4 Occurrence

KurtCobain 04-22-2011 12:05 AM

2 Production

KurtCobain 04-22-2011 12:05 AM

3 Chemical properties

KurtCobain 04-22-2011 12:05 AM

4 History

KurtCobain 04-22-2011 12:06 AM

4.1 Etymology

KurtCobain 04-22-2011 12:06 AM

5 Applications

KurtCobain 04-22-2011 12:06 AM

5.1 Radiation windows

KurtCobain 04-22-2011 12:06 AM

5.2 Mechanical applications

KurtCobain 04-22-2011 12:07 AM

5.2.1 Mirrors

KurtCobain 04-22-2011 12:07 AM

5.3 Magnetic applications

KurtCobain 04-22-2011 12:07 AM

5.4 Nuclear applications

KurtCobain 04-22-2011 12:08 AM

5.5 Acoustics

KurtCobain 04-22-2011 12:08 AM

5.6 Electronic

KurtCobain 04-22-2011 12:08 AM

6 Toxicity

KurtCobain 04-22-2011 12:09 AM

7 See also

KurtCobain 04-22-2011 12:09 AM

8 References

KurtCobain 04-22-2011 12:09 AM

9 Further reading

KurtCobain 04-22-2011 12:10 AM

10 External links

KurtCobain 04-22-2011 12:10 AM

Characteristics

KurtCobain 04-22-2011 12:10 AM

[edit]Physical properties

KurtCobain 04-22-2011 12:11 AM

Beryllium has exceptional flexural rigidity (Young's modulus 287 GPa) and a reasonably high melting point.

KurtCobain 04-22-2011 12:11 AM

The modulus of elasticity of beryllium is approximately 50% greater than that of steel.

KurtCobain 04-22-2011 12:11 AM

The combination of this modulus and a relatively low density results in an unusually fast sound conduction speed in beryllium – about 12.9 km/s at ambient conditions.

KurtCobain 04-22-2011 12:12 AM

Other significant properties are high specific heat (1925 J·kg−1·K−1) and thermal conductivity (216 W·m−1·K−1), which make beryllium the metal with the best heat dissipation characteristics per unit weight.

KurtCobain 04-22-2011 12:12 AM

In combination with the relatively low coefficient of linear thermal expansion (11.4×10−6 K−1), these characteristics result in a unique stability under conditions of thermal loading.[3]

KurtCobain 04-22-2011 12:12 AM

[edit]Nuclear properties

KurtCobain 04-22-2011 12:13 AM

Beryllium has a large scattering cross section for high-energy neutrons, thus effectively slowing the neutrons to the thermal energy range where the cross section is low (about 0.008 barn).

KurtCobain 04-22-2011 12:13 AM

The predominant beryllium isotope 9Be also undergoes a (n,2n) neutron reaction to 8Be, that is, beryllium is a neutron multiplier, releasing more neutrons than it absorbs.

KurtCobain 04-22-2011 12:13 AM

This nuclear reaction is:

KurtCobain 04-22-2011 12:14 AM

9

KurtCobain 04-22-2011 12:14 AM

4Be + n → 2(4

KurtCobain 04-22-2011 12:14 AM

2He) + 2n

KurtCobain 04-22-2011 12:15 AM

Beryllium is also transparent to most wavelengths of X-rays and gamma rays, making it useful for the output windows of X-ray tubes and other such apparatus.

KurtCobain 04-22-2011 12:15 AM

Also, beryllium is a good source for relatively-small numbers of free neutrons in the laboratory.

KurtCobain 04-22-2011 12:15 AM

These are liberated when beryllium nuclei are struck by energetic alpha particles[3] producing this nuclear reaction:

KurtCobain 04-22-2011 12:16 AM

4Be + 4

KurtCobain 04-22-2011 12:16 AM

2He → 12

KurtCobain 04-22-2011 12:17 AM

6C + n

KurtCobain 04-22-2011 12:17 AM

where 4

KurtCobain 04-22-2011 12:17 AM

2He is an alpha particle and 12

KurtCobain 04-22-2011 12:17 AM

6C is a carbon-12 nucleus.[4]

KurtCobain 04-22-2011 12:18 AM

[edit]Isotopes and nucleosynthesis

KurtCobain 04-22-2011 12:18 AM

Main articles: Isotopes of beryllium and beryllium-10

KurtCobain 04-22-2011 12:18 AM

Plot showing variations in solar activity, including variation in 10Be concentration.

KurtCobain 04-22-2011 12:19 AM

Note that the beryllium scale is inverted, so increases on this scale indicate lower 10Be levels
9Be is the only stable isotope.

KurtCobain 04-22-2011 12:19 AM

Thus, it is a monoisotopic element.

KurtCobain 04-22-2011 12:19 AM

Cosmogenic 10Be is produced in the atmosphere of the Earth by the cosmic ray spallation of oxygen and nitrogen.

KurtCobain 04-22-2011 12:20 AM

Cosmogenic 10Be accumulates at the soil surface, where its relatively long half-life (1.36 million years) permits a long residence time before decaying to boron-10.

KurtCobain 04-22-2011 12:20 AM

Thus, 10Be and its daughter products are used to examine natural soil erosion, soil formation and the development of lateritic soils, as well as acting as a proxy for measurement of the variations in solar activity and the age of ice cores.

KurtCobain 04-22-2011 12:20 AM

[5]
The production of 10Be is inversely proportional to solar activity, because the increased solar wind during periods of high solar magnetic activity in turn decreases the flux of galactic cosmic rays that reach the Earth.


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