I (and former ref Perreira) think List is actually right here. Because Wlker hits Talib at the same time that the ball hits the receiver, it's a block not a pick.
If he'd hit TAlib a half-second earlier than he did, however, it's a horrendous pick play and definitely illegal. I don't know that that isn't a fair bit of luck there in terms of the timing of those two events.
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