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Windows 10 keys will work for Windows 11. But again, it must be the same type of version of Windows when exchanging keys. You cannot use a Windows enterprise key to license anything but another enterprise install. But you can use a Win10 Home key to license Win11 Home.
Depending on the setup and existing group policies, you may not be able to simply change the domain account to a workgroup account and then change its password. It shouldn't let you if their IT department is at least somewhat competent with their security. I'm still doubting you'll be able to even leave the domain without credentials for a domain account that's authorized to do so. There should be group policies in place to ensure authentication only comes from specific domain controller(s) or at least cached account credentials. But their IT setup might be dogshit, so who knows.
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