As Fish said, the number listed in Windows won't be the correct key. However, take a look on the bottom of the laptop for a greenish Windows sticker. A lot of the time, manufacturers will put the number there. It should be a 25-digit code, separated by dashes in groups of five.
If you don't have the media and don't want to mess with Acer, you can probably get one via torrent if it came to that.
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